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ress enter to begin the process and note that dd does not provide any on screen information unless there is an error or it finishes. 9MbAbstractThis thesis describes studies into the synthesis and coordination chemistry of ligands containing bulky acidic groups. Both acidic aryl and carboranyl groups have been investigated. Chapter One highlights electronic and structural aspects of ligands investigated and computational techniques employed. They are observed to fluoresce very strongly in the range 372 410 nm. The diethynylbenzene derivatives 1. 